Informing Spectroscopists for Over 40 Years

Articles

BBCEAS is a new cavity-based absorption technique that uses broadband sources rather than lasers. This offers potential improvements in signal-to-noise but often lower spectral resolution compared to techniques where the laser wavelength is scanned. The article concentrates on liquid-phase applications, an interesting new area since most cavity-based absorption studies have been performed on gas-phase species up to now.

Tea is harvested from the bud, the first leaf and the first three leaves up to a maximum of four leaves. Quality decreases from the bud down as the parts become older. This study looks at the use of NIR spectroscopy to determine optimal production using the harvested material.

After an introduction to MALDI, DESI and SIMS, the authors describe their main applications in forensics, as well as the advantages provided in terms of sample preparation over approaches routinely used in toxicological laboratories.

Chemical contaminants in water are of concern to all of us. This article reviews the use of mass spectrometry (MS) in environmental and wastewater analysis.

Industrial environments pose potentially hazardous situations whereby workers may be exposed to various airborne toxic elements in their breathing zone. One of the main aerosol fractions of interest is welding fume, which can be determined with XRF spectrometry.

The authors describe the use of a range of complementary methods to explore cellular, physiological and behavioural mechanisms underlying Al accumulation and toxicity, and its eventual fate, using the pond snail as a model organism.

Research is under way as to the possibility of using high-precision isotopic analysis of metals in a biomedical context. The goal is to develop methods for medical diagnosis on the basis of isotopic analysis of mineral elements in biofluids, for diseases that can otherwise only be established at a later stage or via a more invasive method (e.g., a biopsy) and/or for prognosis purposes. Whilst this work is in a very early stage, it is known that various diseases have an influence on the uptake, metabolism and/or excretion of essential mineral elements and thus, can cause a difference in their isotopic composition in biofluids.

Karsten Hinrichs and Andreas Furchner describe “Infrared mapping spectroscopic ellipsometry”. Recent developments in fundamental and materials research have increased the value of mapping techniques such as ellipsometry. IR ellipsometry, since it operates in the mid-IR fingerprint region, provides complementary information on composition, structural properties and interactions

In situ spectroscopic methods such as infrared, Raman and UV/vis spectroscopy are powerful tools to gain insight into reaction mechanisms and catalyst actions in homogeneously catalysed reactions. These methods and combinations of them offer great potential for the real-time monitoring of reactions in the liquid phase, for mechanistic studies as well as process control and kinetics.

In vivo Raman spectroscopy of skin” is Paul Pudney’s topic. The skin is a most important part of our bodies. There is great interest in studying it to help understand the many skin diseases we are prone to, including cancer, to develop skin care products and, increasingly, as an alternative route to administer pharmaceuticals instead of through the gut. Raman spectroscopy is an excellent tool to study these, and has particular advantages in its ability to do so in vivo.

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